Higher solar yield, less power effort

Glittering solar-paneled roofs atop residential, commercial, and industrial buildings may soon get a new look with the carbon-based organic solar cell or OSC. Thinness and flexibility partly explain why OSCs may be a better alternative to traditional silicon-based cells.

But not all OSCs are created equal. Those based on nonfullerene-acceptors, or NFAs, have now been found to generate electricity efficiently even with a relatively low offset of 0.1 eV. Compared to conventional fullerene-based types, NFA-based OSCs achieve significantly higher power conversion efficiency.

“We then asked ourselves how this was achieved, and what materials we would need to develop in order to obtain the low offset,” says KyotoU’s Yasunari Tamai, whose team made the discovery.

Traditionally, a combination of so-called p-type polymers with n-type fullerene derivatives have been the preferred semiconductors used in OSCs, also called organic photovoltaics, or OPVs. A difference in the energy levels, or offset, of more than 0.3 eV is generally considered necessary to drive photovoltaic conversion. These conventional polymers can provide up to 10-11% of power conversion efficiency.

Tamai adds, “On the other hand, a large offset also drags down the open-circuit voltage. Efficient power conversion requires a trade-off between electric current and voltage in the form of a low offset.”

The best solutions can sometimes be found by thinking outside the box, or in this case, reversing the thinking: lose the fullerene.

Recently, NFA-based OSCs have been found to generate efficient free carriers even with an offset of a mere 0.1 eV, topping regular fullerene-based OSCs by an impressive ten percent or more.

The team used transient absorption spectroscopy to track free carrier generation over time. As when a slalom skier glides down the hill from gate to gate, relaxed charges transfer freely down the energy cascade created in the solar cells.

“We hope that our research will help move the world closer to this practical application of organic solar cell technology to harness the virtually non-depletable energy source from our sun,” concludes Tamai.

Research Report: “Cascaded energy landscape as a key driver for slow yet efficient charge separation with small energy offset in organic solar cells”

(stock image only)

Thanks for being here;

We need your help. The SpaceDaily news network continues to grow but revenues have never been harder to maintain.

With the rise of Ad Blockers, and Facebook – our traditional revenue sources via quality network advertising continues to decline. And unlike so many other news sites, we don’t have a paywall – with those annoying usernames and passwords.

Our news coverage takes time and effort to publish 365 days a year.

If you find our news sites informative and useful then please consider becoming a regular supporter or for now make a one off contribution.

SpaceDaily Contributor

$5 Billed Once
credit card or paypal

SpaceDaily Monthly Supporter
$5 Billed Monthly
paypal only

Solar power down

Paris (ESA) Apr 04, 2022

Solar energy generation keeps on becoming cheaper and more efficient, but some basic limitations will always apply: solar panels can only generate power during the daytime, and much of the sunlight is absorbed by the atmosphere as it shines downward.

So ESA is working on the concept of collecting solar power up in orbit, where sunlight is up to 11 times more intense than across European territory, then beaming it down to the ground for use.

As part of that effort, a new project looks into de … read more