Two studies report: Perovskite-silicon tandem cells that break the 30% efficiency threshold
by Staff Writers
Zurich, Switzerland (SPX) Jul 08, 2023
In two separate studies, researchers present novel methods that enable the fabrication of high-performance perovskite-silicon tandem solar cells with power conversion efficiencies exceeding 30%. Silicon solar cells – the most commonly deployed photovoltaic (PV) technology – are rapidly approaching their theoretical power conversion efficiency (PCE) limit of 29%. One way to increase the efficiency of a solar cell is to optimize the spectrum of sunlight for conversion into energy.
This can be done by stacking two or more interconnected photoactive materials into a singular device, improving the harvesting of solar energy. Combining perovskite and silicon solar cells into a tandem device could provide a promising path toward high-performance PVs.
Here, in two separate studies, researchers present different strategies for developing perovskite-silicon tandem solar cells with a PCE exceeding 30%. “Overcoming this threshold provides confidence that high-performance, low-cost PVs can be brought to the market,” write Stefaan De Wolf and Erkan Aydin in a related Perspective.
In one study, Xin Yu Chin and colleagues show that the uniform deposition of the perovskite top cell on a silicon bottom cell featuring micrometric pyramids – the industry standard configuration – can facilitate high photocurrents in tandem solar cells.
Chin et al. demonstrate that using phosphonic acid additives during the processing sequence of the cells not only improved the perovskite crystallization process, but also helped to alleviate recombination losses.
In a proof-of-concept, the authors fabricated a device with an active area of 1.17 square centimeters that achieved a certified PCE of 31.2%. Taking a different approach, Silvia Mariotti and colleagues show that using an ionic liquid – piperazinium iodide – improved band alignment and enhanced charge extraction at the interface of a trihalide perovskite and the electron-transport layer by creating a positive dipole. Using this modification, Mariotti et al. developed a perovskite-silicon tandem solar cell that demonstrated an impressive open circuit voltage of up to 2.0 volts and a certified PCE of up to 32.5%.